Electrolytic Galvanizing: How It Works

How Does Electrolytic Galvanizing Work?

Electrolytic galvanizing, also known as galvanic galvanizing, is a coating system that occurs by immersion in an electrolytic solution containing zinc salts. It is the result of a series of processes that lead to the final product. Indeed, for a more effective coating, the material is subjected to several preliminary operations:

• Pre-degreasing;
• Pickling;
• Degreasing.

Subsequently, the material is immersed in the solution with zinc salts, and then a current is passed between the piece and the solution.
This last phase is necessary to better adhere the zinc layer to the element. There are two main types of electrolytic galvanization:

1. Cold electrolytic galvanization with static automatic plants: the pieces to be worked are hung on frames moved by an overhead crane. The current is transported to the pieces that will be worked on cold through the frames. This type of treatment is ideal for large-sized artifacts and fine threads.

2. Cold electrolytic galvanization with a barrel plant: the pieces to be worked are placed on hooks that allow electrical contact. This comes from a barrel that rotates on its axis and allows the transfer of contact. This second type of processing allows reducing the labor needed for each piece.

The type of processing to be used is chosen based on the criteria that the piece must have. In general, electrolytic galvanization ensures excellent protection from rust, and therefore, an optimal performance of the product thus galvanized compared to other galvanization systems.
But what differentiates the various techniques?

What Changes Between the Different Galvanizations

Among the most common galvanization systems, there are technical differences that make each process different from the other:

• Both hot-dip galvanization and electrolytic galvanization occur by immersion. In the first, the piece is immersed in vats of molten zinc at 450°, while in the second, as already specified above, the material is immersed in an electrolytic solution containing zinc salts.

• Spray galvanization, as the term itself suggests, is a process that occurs by spraying. Using guns equipped with a melting and atomizing device, the previously powdered zinc layer is sprayed onto the material.

• Cold galvanization is a real painting with synthetic resins.

Each system has its specific characteristics but, the final intent of each is the protection of the steel material. Whatever galvanization process is chosen, the processing must ensure uniformity of the product and, therefore, complete protection. It can be said that, among all the types of galvanization available, electrolytic galvanization is used on steel and ferrous alloys.
Moreover, it is a treatment with a lower environmental impact.

White Electrolytic Galvanization

In the previous paragraphs, we have seen the different operational phases of galvanic galvanization and how it is articulated. An important phase of the processing, on which the aesthetic value of the product depends, is the finishing or passivation. During this final step, the various products acquire different colors depending on the protective sealants used. For example, white galvanization gives the product an almost blue appearance. The categories of white galvanized products are numerous, such as:

• Screws
• Nuts
• Washers
• Self-tapping screws
• Self-drilling screws
• Lifting accessories

How Long Does Electrolytic Galvanization Last?

Talking about the durability of galvanization means talking about the thickness of the electrolytic galvanization and, therefore, the thickness of the zinc layer deposited on the material. Indeed, depending on the specific requirements requested, the application, and the destination of the piece, a protective thickness will be applied to it, which will condition its durability over time.

A determining factor in the longer or shorter lifespan of a manufactured good is the environment. In fact, if the galvanized components are destined for highly corrosive environments (for example, the chemical sector or applications in marine environments), the treatment will have a shorter duration compared to other conditions.

Therefore, based on the final use and the corrosiveness rate of the environment, it will be the responsibility of the competent technical office to determine which specifications the product must refer to and choose between galvanized steel materials and stainless steel materials.

UNI ISO 2081: Standard on Electrolytic Galvanization

The standard that regulates electrolytic galvanization is UNI ISO 2081, which came into force on April 12, 2018.

This standard defines the process of such a processing technique and its variations. In particular, the standard establishes the electrolytic requirements of zinc with additional treatments on iron or steel. The UNI ISO 2081 on galvanization coatings is linked to the UNI ISO 4520 standard, which establishes the criteria concerning passivations. Products certified according to such standards, therefore, comply with the expected standards.

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